Remember the VPN only protects the connections made to it. Any other window/tab/browser that is not part of that connection or doesn't make a connection of it's own is not part of the VPN. If the browser is inside the VPN, not just connected, then it has the full benefits of the VPN for all windows/tabs and then only if the connection is part of or has a connection has a to it. Most VPNs are usually only allowed to go to places that are not part of that VPN that are allowed by the company. All others are blocked.
You aim a browser to a site by typing in it's address. I'm sorry I should have said by going to.
It is not useless as the VPN was set up to protect the company not you. For an individual VPNs are useless unless you want to control who has access to you or your network. Then it would be useless for the internet as you would have to let your browser go to all sites that you want then you still wouldn't have any protection unless those sites are allowed to become part of your VPN and they are connected at the time. As the protection given by that VPN only protects it's own network. Remember VPNs are only networks nothing else.