Computer Hardware NiMH cells emit smell of gas

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Subject Author Date
NiMH cells emit smell of gas Jon D 05-21-06
Posted by Jon D on May 21, 2006, 7:29 pm
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I have a rapid charger with a fold down cover. When I charge a couple
eof AA or AAA cells there is a smell of gas in the chamber under the
lid.

Seems to me that the cells are getting overcharge and are venting.

This is a charger with a sensor for "negative delta-V" to edermine the
end of the charging. The cells are about 10 to 15C above room
temperatre.

Is the charger cooking my cells? Or is the smell noticeable because of
the enclosed battery compartment?


Posted by kony on May 21, 2006, 10:50 pm
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wrote:

>I have a rapid charger with a fold down cover. When I charge a couple
>eof AA or AAA cells there is a smell of gas in the chamber under the
>lid.
>
>Seems to me that the cells are getting overcharge and are venting.

Yes

>
>This is a charger with a sensor for "negative delta-V" to edermine the
>end of the charging. The cells are about 10 to 15C above room
>temperatre.

Possibly the cells had vented previously and the seal is now
open. I would throw them away, then wonder why they'd
gotten hot enough to vent previously. Some Delta-V chargers
only have a Delta-V detection but not temp monitoring, so if
a cell were fully charged and an event like AC power flicker
occured at long enough duration to reset the charger, it
might then start charging at the fast-charge rate again, but
there will be no Delta-V to detect since the cells were past
that stage already... so if they get too hot, they vent
which was better than an explosion.

At the very least if you continue to use that charger, you
might not want to fold down the cover to increase passive
cooling. There are other things you could do like pointing
a fan at the cells but it seems a hassle instead of just
seeking a different charger, IF it seems the charger doesn't
have the temp cutoff feature.


>
>Is the charger cooking my cells? Or is the smell noticeable because of
>the enclosed battery compartment?


No with undamaged cells and proper charging (not
overcharging) there is no gas escaping to be building up in
the compartment.

Posted by UCLAN on May 22, 2006, 1:43 am
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Jon D wrote:

> I have a rapid charger with a fold down cover. When I charge a couple
> eof AA or AAA cells there is a smell of gas in the chamber under the
> lid.
>
> Seems to me that the cells are getting overcharge and are venting.

You need a better charger, like a Maha MH-C401FS.

http://www.thomas-distributing.com/mhc401fs.htm

Posted by Evgenij Barsukov on May 22, 2006, 1:39 pm
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Jon D wrote:
> I have a rapid charger with a fold down cover. When I charge a couple
> eof AA or AAA cells there is a smell of gas in the chamber under the
> lid.
>
> Seems to me that the cells are getting overcharge and are venting.
>
> This is a charger with a sensor for "negative delta-V" to edermine the
> end of the charging. The cells are about 10 to 15C above room
> temperatre.
>
> Is the charger cooking my cells? Or is the smell noticeable because of
> the enclosed battery compartment?
>
Not all cells can be rapid-charged, some have just too high impedance
for that, as result they would heat up and went.
Good rapid chargers come with the cells designed for rapid charging,
or must at least have a list of recommended cells.

Regards,
Evgenij

Posted by on May 22, 2006, 3:24 pm
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Jon D wrote:

> I have a rapid charger with a fold down cover. When I charge a couple
> eof AA or AAA cells there is a smell of gas in the chamber under the
> lid.
>
> Seems to me that the cells are getting overcharge and are venting.
>
> This is a charger with a sensor for "negative delta-V" to edermine the
> end of the charging. The cells are about 10 to 15C above room
> temperatre.
>
> Is the charger cooking my cells? Or is the smell noticeable because of
> the enclosed battery compartment?

deltaV doesn't work very well with NiMH cells because NiMH voltage
either doesn't drop or drops only a very small amount when full charge
approaches.

Some chargers are much worse than others. The best use not only deltaV
but also temperature, temperature difference, rate of temperature
rise, and, as a last resort, time.


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