Some information sources indicate there is no difference between T568A and T568B wiring besides what color is used at which pin position. This implies that as long as association between pins is correct (reversed in the case of a crossover cable), a patch cable (8P8C on each end) will work fine whether wired for T568A or T568B. It would be assumed the "big deal" is just when the color has to be used to identify something, such as when wiring one end of a cable to something other than an 8P8C plug.
But some other information sources suggest that using T568A when T568B is in standard use, or the reverse, that the electrical quality is slightly degraded even though things generally work. If this information is true, then that would suggest some kind of _electrical_ or _metallic_ difference in the wires, and not just the insulation color. As far as I am aware, the additives to insulation to create the color has no effect.
Could the wires in a CAT5/CAT5e/CAT6 cable be _electrically_ different in some way, such as a different impedance (I thought it was all supposed to be 100 ohms within a twisted pair, or a different cross sectional area 9and thus affect the resistive loss)?
I still look forward to the day that computer interconnections begin using symmetric bidirectional cabling so we can stop having to deal with various wiring schemes and get rid of crossover cables and such.